FAQ

Kynar®

What is Kynar®?

Kynar® is a registered trademark of Arkema, Inc. Kynar® is also an amazing polymer that solves problems and creates manufacturing innovations every day.

ISO 13485 Certification

Our Strong-Ty® PVDF cable ties are manufactured at a facility that follows ISO 13485 manufacturing procedures.

Please contact us if you would like a copy.

Kynar® USP Class VI test report

Our cable ties and filaments meet USP Class VI certification requirements. This is the last word in purity.

Fluorinar™ PVDF Filament

What color and diameter options are available?

Fluorinar-C™ 1.75mm & 2.85 mm (white and black)

Fluorinar-H™ 1.75mm & 2.85 mm (white)

What are the differences between the various Fluorinar™ PVDF filaments?

PVDF is commonly used throughout industry (semicon, biopharm, nuclear, chemical process) in the homopolymer form. This corresponds to our Fluorinar-H™ material. PVDF has two fluorine and two hydrogen atoms in each repeat unit. It can be thought of as the offspring of PTFE (4 fluorine atoms and PE (4 hydrogen atoms). Unlike PTFE, PVDF is fully melt-processible. The high crystallinity of PVDF makes adhesion to the build plate difficult. There is a change in the volume of semicrystalline plastics such as PVDF during the transition from the amorphous melt phase to the semicrystalline solid. This creates surface stress between the print and the build plate. This stress can be managed through careful part design (no sharp corners, fillet transitions from the bottom to the side, use of adhesive, etc.) Our Fluorinar-H™ filament represents this 50+ year PVDF legacy.

The Fluorinar-C™ filament is made from a Kynar® PVDF copolymer. It is polymerized with the VDF monomer and hexafluoropropylene (HFP) monomer. 100% HFP is a fluoroelastomer known by the old DuPont tradename Viton®. Fluorinar-C™ has increased flexibility, slightly lower crystallinity and melting temperatures and slightly different chemical resistance. The most important advantage of this filament is increased build plate adhesion which results in better prints

What length of filament is on a spool?


A 1 kg spool of 1.75 mm Fluorinar™ filament has approximately 785 feet (239m).

A 1 kg spool of 2.85 mm Fluorinar™ filament has approximately 300 feet (91m).

How will a Fluorinar™ print hold up under a specific chemical application?

The effects of chemical exposure to our Fluorinar™ materials is extremely important. We provide a table of the chemical resistance of our Fluorinar™ filaments here. However, reality can be much more difficult with variations in temperature, concentrations and varieties of chemicals often present. To help your material evaluation, we recommend that you print some tensile-test samples and expose them to your specific environment. An STL print file for this sample is found at the Thingiverse web site. Once samples have been printed, they can be weighed and placed into your environment. You can drill a small hole in the end of the dog bone and tie a PTFE line used for tooth floss onto the sample. After 1, 2 or 4 weeks these samples can be removed and weighed again. Lack of significant weight gain is often a good indicator of material compatibility to your application.

We also prove some general guidance on the chemical compatibility of our filament.

Printing with Fluorinar™ PVDF Filament

What 3D printer and slicer does Nile recommend?

The main requirement for a successful print is a heated build plate. The printer you select must be able to maintain a heated glass build plate at 100C. We have tried many printers and so have our customers. Collectively we have converged on the Ultimaker models. These are not priced as an entry-level machine, but a generally considered an industrial/prosumer choice. We have found the Ultimaker machines provide very consistent results with almost zero downtime. Ultimaker also provides the Cura slicer software at no additional cost. This slicer is continually updated and improves with every release. Ultimaker machines and the Cura software make a combination that is hard to beat.

What print parameters should I use for a successful print?

  • Print on a glass bed heated to 100 C.
  • Apply a single continuous layer of Elmer’s disappearing purple glue on the glass build plate for adhesion. Other PVA adhesives have not been as effective.
  • Print with a single layer 10 – 15 mm brim attached to the part.  This is often not required for Fluorinar-C™
  • Maximize part surface area in contact with the print bed
  • .Set extrusion temperature 250 – 260 C.
  • Layer height can be 0.1 – 0.2 mm.
  • Print speed should be around 20 – 40 mm/s.
  • If the part is small it will help to print in duplicate as the most recent layer on the first part is allowed to cool while the layer on the second part is printing.
  • Fluorinar-H™ likes to run hot. We never use a fan with this material. 
  • When using Fluorinar-C™ for larger prints, a fan can be used to increase print speed up to 70 mm/s depending on part geometry.  Keep an eye on things. 
  • If interlayer bonding does not appear to be working then the fan or print speed can be reduced.
  • When printing 3DBenchy with Fluorinar-C™ we run the fan up to 100% in order to get the rod holder and smokestack features nice and round.

Additional printing guidance can be found here.

How much shrinkage can I expect to see when using Fluorinar™ filaments?

To determine the amount of shrinkage in a printed part, we printed examples of the 20 mm XYZ calibration cube.
This STL file is available from Thingiverse.

Filament: Fluorinar-C™ (white)
Layer Height: 0.2 mm
Infill: 30%
X-axis = 19.80 mm (-1.00%)
Y-axis = 19.87 mm (-0.65%)
Z-axis = 19.65 mm (-1.75%)

Filament: Fluorinar-C™ (black)
Layer Height: 0.2 mm
Infill: 30%
X-axis = 19.82 mm (-0.90%)
Y-axis = 19.98 mm (-0.10%)
Z-axis = 19.91 mm -(0.45%)

What support materials work best with Fluorinar™ filament?

If you can print the support directly to the build plate then HIPS or a TPU are possible candidate materials.

With HIPS, you won’t get adhesion between the support and the Fluorinar™ filament, but the HIPS will help bridge a gap between two locations. For instance, if you were printing the letter H, HIPS would help bridge the horizontal gap. If you tried to print the letter F, the two unconnected horizontal parts of the letter would not bond to the HIPS and would lift and curl. We print the HIPS at close to the same temperature as we do the Fluorinar™ PVDF: 240C with a 100C build plate temperature, HIPS dissolves in acetone and limonene. Acetone is a slow-acting solvent for PVDF so you want to be careful. Exposure of your PVDF print to acetone will cause the interlayers to disbond. Limonene has a boiling temperature around the softening point of the Fluorinar filaments, so if you use heat to accelerate the HIPS dissolving process be careful, otherwise the PVDF print will turn into a melted mess at the bottom of the beaker.

TPU is an interesting material. If you have ever purchased the foaming sealant from Home Depot, this is a form of polyurethane and it sticks to almost everything. It can be a real mess. There is a slight amount of adhesion between the TPU and the PVDF, so it does make a better support material. However, there is no easy way to dissolve this so mechanical methods are the only way to remove the support. Again, we print the TPU at the same temperature at the Fluorinar™ PVDF. Also, because of the similar temperatures, there is some cross-contamination between the materials. If you are printing in our white Fluorinar-C™ filament with a black TPU support, you will find it difficult to remove all of the TPU and will be left with small TPU specs and inclusions. If you print with a white TPU then these inclusions are not readily visible.

Follow-up question: Can you print either HIPS or TPU directly onto PVDF?

Yes and no. If you have an extended brim around the part made from the support material then you print the support material directly over the print as long as the support material is in contact with the brim. For instance, if you were printing the letter B you could surround the letter with a brim made from the support material and then fill in the interior regions with support material printed directly onto the Fluorinar™ PVDF.

I don't want to buy filament and print, but I have a part that I would like printed with PVDF. Can you help me?

We get it. Not everyone has the equipment, time or interest in printing. Nile Polymers has teamed up with Noah Kelley at Granville 3D Printing. Printing parts is what Noah does every day. Reach out to him and see what he recommends. His email is

granville3dprinting@gmail.com

Strong-Ty® Cable Ties

Are Strong-Ty® Cable TIes sterile?

Strong-Ty® are manufactured and packaged in a clean room. However, our ties are non-sterile. Our PVDF cable ties can withstand radiation or chemical sterilization processes without loss of mechanical properties.

How will irradiation of the Strong-Ty® Cable Ties (for sterilization) affect cable tie performance?

Strong-Ty® PVDF cable ties are going to perform just fine after sterilization.

Of all the fluoropolymers available, PVDF performs the best in conditions of ionizing radiation and typically shows an increase in tensile strength and toughness without sacrificing elongation. Kynar® PVDF is frequently used to protect the interior surfaces of gloveboxes. These isolated enclosures are used by the US Government for the handling and processing of fissile materials. Some of this work also involves aggressive mineral acids. Many of these containment environments are more than 30 years old and continue to be used every day without incident. This amazing service life is a great endorsement of Kynar® PVDF.

I have a custom cable tie requirement - can Nile Polymers help me?

Yes!

Please contact us and we will respond within 24 business hours.

Purisan™ PVDF mixers

What Purisan™ Kynar® industrial mixer styles are available?

Right now we are delivering marine-style impellers in 4″, 5″ and 6″ diameters. Contact us if there is an impeller design you would like us to consider.

How do I attach a mixer to my equipment?

Our Purisan™ PVDF industrial mixers have a smooth bore that can be threaded for mixer shaft attachment.

I have a custom mixer design that requires a USP class VI material - can Nile Polymers help me?

Yes!

We know a lot about injection molding and 3D printing of PVDF.

Please contact us and we will respond within 24 business hours.

Shipping

How much does shipping cost?

Shipping is auto-calculated at checkout. We love Shopify!

When will I get my tracking number?

You will get an email with the tracking number when the shipping label is printed.

How soon will my order ship?

Off-the-shelf items will ship within 24 hours of order placement. If there is a delay, Nile will contact you with a revised shipment date.

Didn't find the answer here? Ask!